Tuesday, March 28, 2017

Chemistry XII+ - Solid State 07

Question : 1
(skipped)
Excess of lithium makes LiCl crystal
Options:
Pink colour

Violet colour

Red colour

No colour
Solution :
Pink colour, as metal excess due to anion vacancy.
You scored 0 of 1
Question : 2
(skipped)
Intrinsic or thermodynamic defects includes
Options:
Schottky defect

Metal excess defect

Metal deficiency defect

All of these
Solution :
Intrinsic or thermodynamic defect are stoichiometric defect
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Question : 3
(skipped)
When AgCl is doped by cadmium chloride, then
Options:

Cationic vacancy is triple in number than that of cadmium ions

Cationic vacancy is double in number than that of cadmium ions
Cationic vacancy is equal in number than that of cadmium ions

No cationic vacancy
Solution :
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Question : 4
(skipped)
Which is not correct regarding Frenkel defect?
Options:

It creates both vacancy defect and interstitial defect

Smaller ion (usually cations) is dislocated from its site

It decreases the stability of the solid crystal
It decreases dielectric constant of the medium
Solution :
Frenkel defect increases dielectric constant of the medium.
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Question : 5
(skipped)
Which is mismatched regarding the examples indicates?
Options:

Anti-ferroelectric – PbZrO3

Ferroelectric – BaTiO3, KH2PO4

Anti-ferromagnetic – MnO
Ferrimagnetic – CrO2, MgFe2O4
Solution :
CrO2is ferromagnetic.
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Question : 6
(skipped)
If NaCl has 10% Schottky defect, then the number of formula unit of NaCl per unit cell will be
Options:

4
3.6

0.4

0.1
Solution :
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Question : 7
(skipped)
In NaCl structure one Schottky defect is present per how many ions?
Options:

106

1010
1016

1022
Solution :
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Question : 8
(skipped)
The correct statement among following is
Options:

On heating substance lose their ferrimagnetism and becomes paramagnetic

There is large forbidden zone present in insulators between valence and conduction band

Ferrimagnetic substances would make better permanent magnets then ferromagnetic substances
Both (1) & (2)
Solution :
Ferromagnetic substances make better permanent magnets.
You scored 0 of 1
Question : 9
(skipped)
The percentage by number of ferrous ions present in Fe0.95O will be
Options:

10.5%

15%

85%
89.5%
Solution :
You scored 0 of 1
Question : 10
(skipped)
If NaCl is doped by 10–5% SiCl4, then the concentration of cationic vacancy will be
Options:

1.204 × 1017
1.806 × 1017

1.806 × 1019

2.408 × 1017
Solution :

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